Tuning Defects to Facilitate Hydrogen Storage in Core-shell MIL-101(Cr)atUiO-66(Zr) Nanocrystals

Jianwei Ren; Henrietta W. Langmi; Nicholas M. Musyoka; Mkhulu Mathe; Xiangdong Kang; Shijun Liao

doi:10.1016/j.matpr.2015.08.026

Tuning Defects to Facilitate Hydrogen Storage in Core-shell MIL-101(Cr)atUiO-66(Zr) Nanocrystals

Jianwei Ren
, Henrietta W. Langmi
, Nicholas M. Musyoka
, Mkhulu Mathe
, Xiangdong Kang
, Shijun Liao

Research output: Journal Publication › Article › peer-review

21 Citations (Scopus)

Abstract

In this work, the existence of structural defects in core-shell MIL-101(Cr)atUiO-66(Zr) and pure UiO-66(Zr) wereproposed. It was found that longer synthesis time leads to larger crystals, which are however not perfect as they morphologically appear to be. During the synthesis, the 1,4-benzenedicarboxylic acid (BDC) linker and modulator (HCOOH) may play competitive roles. The modulator employed does not only modulate the crystal growth, but also contributes in the formation of the MOF framework and promotes defects. Although structural defects would facilitate hydrogen storage in MOF structures, they need to be tuned to an optimum level for hydrogen adsorption purpose.

Original language	English
Pages (from-to)	3964-3972
Number of pages	9
Journal	Materials Today: Proceedings
Volume	2
Issue number	7
DOIs	https://doi.org/10.1016/j.matpr.2015.08.026
Publication status	Published - 2015
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Free Keywords

Hydrogen storage
Metal-organic frameworks
Modulated synthesis
Structural defects

ASJC Scopus subject areas

General Materials Science

Access to Document

10.1016/j.matpr.2015.08.026

Cite this

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title = "Tuning Defects to Facilitate Hydrogen Storage in Core-shell MIL-101(Cr)atUiO-66(Zr) Nanocrystals",

abstract = "In this work, the existence of structural defects in core-shell MIL-101(Cr)atUiO-66(Zr) and pure UiO-66(Zr) wereproposed. It was found that longer synthesis time leads to larger crystals, which are however not perfect as they morphologically appear to be. During the synthesis, the 1,4-benzenedicarboxylic acid (BDC) linker and modulator (HCOOH) may play competitive roles. The modulator employed does not only modulate the crystal growth, but also contributes in the formation of the MOF framework and promotes defects. Although structural defects would facilitate hydrogen storage in MOF structures, they need to be tuned to an optimum level for hydrogen adsorption purpose.",

keywords = "Hydrogen storage, Metal-organic frameworks, Modulated synthesis, Structural defects",

author = "Jianwei Ren and Langmi, \{Henrietta W.\} and Musyoka, \{Nicholas M.\} and Mkhulu Mathe and Xiangdong Kang and Shijun Liao",

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year = "2015",

doi = "10.1016/j.matpr.2015.08.026",

language = "English",

volume = "2",

pages = "3964--3972",

journal = "Materials Today: Proceedings",

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number = "7",

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T1 - Tuning Defects to Facilitate Hydrogen Storage in Core-shell MIL-101(Cr)atUiO-66(Zr) Nanocrystals

AU - Ren, Jianwei

AU - Langmi, Henrietta W.

AU - Musyoka, Nicholas M.

AU - Mathe, Mkhulu

AU - Kang, Xiangdong

AU - Liao, Shijun

PY - 2015

Y1 - 2015

N2 - In this work, the existence of structural defects in core-shell MIL-101(Cr)atUiO-66(Zr) and pure UiO-66(Zr) wereproposed. It was found that longer synthesis time leads to larger crystals, which are however not perfect as they morphologically appear to be. During the synthesis, the 1,4-benzenedicarboxylic acid (BDC) linker and modulator (HCOOH) may play competitive roles. The modulator employed does not only modulate the crystal growth, but also contributes in the formation of the MOF framework and promotes defects. Although structural defects would facilitate hydrogen storage in MOF structures, they need to be tuned to an optimum level for hydrogen adsorption purpose.

AB - In this work, the existence of structural defects in core-shell MIL-101(Cr)atUiO-66(Zr) and pure UiO-66(Zr) wereproposed. It was found that longer synthesis time leads to larger crystals, which are however not perfect as they morphologically appear to be. During the synthesis, the 1,4-benzenedicarboxylic acid (BDC) linker and modulator (HCOOH) may play competitive roles. The modulator employed does not only modulate the crystal growth, but also contributes in the formation of the MOF framework and promotes defects. Although structural defects would facilitate hydrogen storage in MOF structures, they need to be tuned to an optimum level for hydrogen adsorption purpose.

KW - Hydrogen storage

KW - Metal-organic frameworks

KW - Modulated synthesis

KW - Structural defects

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DO - 10.1016/j.matpr.2015.08.026

M3 - Article

AN - SCOPUS:84949845718

SN - 2214-7853

VL - 2

SP - 3964

EP - 3972

JO - Materials Today: Proceedings

JF - Materials Today: Proceedings

IS - 7

ER -

Tuning Defects to Facilitate Hydrogen Storage in Core-shell MIL-101(Cr)atUiO-66(Zr) Nanocrystals

Abstract

UN SDGs

Free Keywords

ASJC Scopus subject areas

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