Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

Xue Han; Richard A. Bourne; Martyn Poliakoff; Michael W. George

doi:10.1039/b914074c

Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

Xue Han
, Richard A. Bourne
, Martyn Poliakoff^*
, Michael W. George

^*Corresponding author for this work

Research output: Journal Publication › Article › peer-review

32 Citations (Scopus)

Abstract

Photochemically generated singlet oxygen,¹O₂, has been reacted with four different substrates in supercritical carbon dioxide. By using fluorous surfactants and a co-solvent to solubilise more polar photosensitisers and reactants respectively, the applicability of the system is greatly enhanced.

Original language	English
Pages (from-to)	1787-1792
Number of pages	6
Journal	Green Chemistry
Volume	11
Issue number	11
DOIs	https://doi.org/10.1039/b914074c
Publication status	Published - 3 Nov 2009
Externally published	Yes

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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10.1039/b914074c

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title = "Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide",

abstract = "Photochemically generated singlet oxygen,1O2, has been reacted with four different substrates in supercritical carbon dioxide. By using fluorous surfactants and a co-solvent to solubilise more polar photosensitisers and reactants respectively, the applicability of the system is greatly enhanced.",

author = "Xue Han and Bourne, \{Richard A.\} and Martyn Poliakoff and George, \{Michael W.\}",

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doi = "10.1039/b914074c",

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AU - Poliakoff, Martyn

AU - George, Michael W.

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Y1 - 2009/11/3

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AB - Photochemically generated singlet oxygen,1O2, has been reacted with four different substrates in supercritical carbon dioxide. By using fluorous surfactants and a co-solvent to solubilise more polar photosensitisers and reactants respectively, the applicability of the system is greatly enhanced.

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U2 - 10.1039/b914074c

DO - 10.1039/b914074c

M3 - Article

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SN - 1463-9262

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JO - Green Chemistry

JF - Green Chemistry

IS - 11

ER -

Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

Abstract

ASJC Scopus subject areas

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