Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior

Youbing Li; Mian Li; Jun Lu; Baokai Ma; Zhipan Wang; Ling-Zhi Cheong; Kan Luo; Xianhu Zha; Ke Chen; Per O. A. Persson; Lars Hultman; Per Eklund; Cai Shen; Qigang Wang; Jianming Xue; Shiyu Du; Zhengren Huang; Zhifang Chai; Qing Huang

doi:10.1021/ACSNANO.9B03530

Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior

Youbing Li
, Mian Li
, Jun Lu
, Baokai Ma
, Zhipan Wang
, Ling-Zhi Cheong
, Kan Luo
, Xianhu Zha
, Ke Chen
, Per O. A. Persson
, Lars Hultman
, Per Eklund
, Cai Shen
, Qigang Wang
, Jianming Xue
, Shiyu Du
, Zhengren Huang
, Zhifang Chai
, Qing Huang

Research output: Journal Publication › Article › peer-review

Abstract

A Ti3(AlxCu1–x)C2 phase with Cu atoms with a degree of ordering in the A plane is synthesized through the A site replacement reaction in CuCl2 molten salt. The weakly bonded single-atom-thick Cu layers in a Ti3(AlxCu1–x)C2 MAX phase provide actives sites for catalysis chemistry. As-synthesized Ti3(AlxCu1–x)C2 presents unusual peroxidase-like catalytic activity similar to that of natural enzymes. A fabricated Ti3(AlxCu1–x)C2/chitosan/glassy carbon electrode biosensor prototype also exhibits a low detection limit in the electrochemical sensing of H2O2. These results have broad implications for property tailoring in a nanolaminated MAX phase by replacing the A site with late transition elements.

Original language	English
Pages (from-to)	9198−9205
Number of pages	7
Journal	ACS Nano
Issue number	13
DOIs	https://doi.org/10.1021/ACSNANO.9B03530
Publication status	Published - 2019
Externally published	Yes

Keywords

nanolaminate
MAX phase
copper
catalysis
replacement reaction

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10.1021/ACSNANO.9B03530

Cite this

Li, Y., Li, M., Lu, J., Ma, B., Wang, Z., Cheong, L.-Z., Luo, K., Zha, X., Chen, K., Persson, P. O. A., Hultman, L., Eklund, P., Shen, C., Wang, Q., Xue, J., Du, S., Huang, Z., Chai, Z., & Huang, Q. (2019). Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior. ACS Nano, (13), 9198−9205. https://doi.org/10.1021/ACSNANO.9B03530

@article{aa8b8832dcb743ac9d444241de8b46f0,

title = "Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior",

abstract = "A Ti3(AlxCu1–x)C2 phase with Cu atoms with a degree of ordering in the A plane is synthesized through the A site replacement reaction in CuCl2 molten salt. The weakly bonded single-atom-thick Cu layers in a Ti3(AlxCu1–x)C2 MAX phase provide actives sites for catalysis chemistry. As-synthesized Ti3(AlxCu1–x)C2 presents unusual peroxidase-like catalytic activity similar to that of natural enzymes. A fabricated Ti3(AlxCu1–x)C2/chitosan/glassy carbon electrode biosensor prototype also exhibits a low detection limit in the electrochemical sensing of H2O2. These results have broad implications for property tailoring in a nanolaminated MAX phase by replacing the A site with late transition elements.",

keywords = "nanolaminate, MAX phase, copper, catalysis, replacement reaction",

author = "Youbing Li and Mian Li and Jun Lu and Baokai Ma and Zhipan Wang and Ling-Zhi Cheong and Kan Luo and Xianhu Zha and Ke Chen and Persson, \{Per O. A.\} and Lars Hultman and Per Eklund and Cai Shen and Qigang Wang and Jianming Xue and Shiyu Du and Zhengren Huang and Zhifang Chai and Qing Huang",

year = "2019",

doi = "10.1021/ACSNANO.9B03530",

language = "English",

pages = "9198−9205",

journal = "ACS Nano",

issn = "1936-0851",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior

AU - Li, Youbing

AU - Li, Mian

AU - Lu, Jun

AU - Ma, Baokai

AU - Wang, Zhipan

AU - Cheong, Ling-Zhi

AU - Luo, Kan

AU - Zha, Xianhu

AU - Chen, Ke

AU - Persson, Per O. A.

AU - Hultman, Lars

AU - Eklund, Per

AU - Shen, Cai

AU - Wang, Qigang

AU - Xue, Jianming

AU - Du, Shiyu

AU - Huang, Zhengren

AU - Chai, Zhifang

AU - Huang, Qing

PY - 2019

Y1 - 2019

N2 - A Ti3(AlxCu1–x)C2 phase with Cu atoms with a degree of ordering in the A plane is synthesized through the A site replacement reaction in CuCl2 molten salt. The weakly bonded single-atom-thick Cu layers in a Ti3(AlxCu1–x)C2 MAX phase provide actives sites for catalysis chemistry. As-synthesized Ti3(AlxCu1–x)C2 presents unusual peroxidase-like catalytic activity similar to that of natural enzymes. A fabricated Ti3(AlxCu1–x)C2/chitosan/glassy carbon electrode biosensor prototype also exhibits a low detection limit in the electrochemical sensing of H2O2. These results have broad implications for property tailoring in a nanolaminated MAX phase by replacing the A site with late transition elements.

AB - A Ti3(AlxCu1–x)C2 phase with Cu atoms with a degree of ordering in the A plane is synthesized through the A site replacement reaction in CuCl2 molten salt. The weakly bonded single-atom-thick Cu layers in a Ti3(AlxCu1–x)C2 MAX phase provide actives sites for catalysis chemistry. As-synthesized Ti3(AlxCu1–x)C2 presents unusual peroxidase-like catalytic activity similar to that of natural enzymes. A fabricated Ti3(AlxCu1–x)C2/chitosan/glassy carbon electrode biosensor prototype also exhibits a low detection limit in the electrochemical sensing of H2O2. These results have broad implications for property tailoring in a nanolaminated MAX phase by replacing the A site with late transition elements.

KW - nanolaminate

KW - MAX phase

KW - copper

KW - catalysis

KW - replacement reaction

UR - https://publons.com/publon/21414380/

U2 - 10.1021/ACSNANO.9B03530

DO - 10.1021/ACSNANO.9B03530

M3 - Article

SN - 1936-0851

SP - 9198−9205

JO - ACS Nano

JF - ACS Nano

IS - 13

ER -

Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior

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Keywords

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