Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer

Mark R. Warren; Simon K. Brayshaw; Andrew L. Johnson; Stefanie Schiffers; Paul R. Raithby; Timothy L. Easun; Michael W. George; John E. Warren; Simon J. Teat

doi:10.1002/anie.200901706

Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η¹-ONO)C1] isomer

Mark R. Warren
, Simon K. Brayshaw
, Andrew L. Johnson
, Stefanie Schiffers
, Paul R. Raithby
, Timothy L. Easun
, Michael W. George
, John E. Warren
, Simon J. Teat

Research output: Journal Publication › Article › peer-review

82 Citations (Scopus)

Abstract

Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η¹-NO₂)Cl] have, for the first time, identified a system which undergoes a reversible 100 % conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η¹-ONO)Cl] isomer.

Original language	English
Pages (from-to)	5711-5714
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	31
DOIs	https://doi.org/10.1002/anie.200901706
Publication status	Published - 20 Jul 2009
Externally published	Yes

Free Keywords

Linkage isomerism
Metastable compounds
Nitrites
Photocrystallography
Raman spectroscopy

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200901706

Cite this

Warren, M. R., Brayshaw, S. K., Johnson, A. L., Schiffers, S., Raithby, P. R., Easun, T. L., George, M. W., Warren, J. E., & Teat, S. J. (2009). Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η¹-ONO)C1] isomer. Angewandte Chemie - International Edition, 48(31), 5711-5714. https://doi.org/10.1002/anie.200901706

@article{57470f3fdb2546a683c46e621b68cd57,

title = "Reversible 100 \% linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer",

abstract = "Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η1-NO2)Cl] have, for the first time, identified a system which undergoes a reversible 100 \% conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η1-ONO)Cl] isomer.",

keywords = "Linkage isomerism, Metastable compounds, Nitrites, Photocrystallography, Raman spectroscopy",

author = "Warren, \{Mark R.\} and Brayshaw, \{Simon K.\} and Johnson, \{Andrew L.\} and Stefanie Schiffers and Raithby, \{Paul R.\} and Easun, \{Timothy L.\} and George, \{Michael W.\} and Warren, \{John E.\} and Teat, \{Simon J.\}",

year = "2009",

month = jul,

day = "20",

doi = "10.1002/anie.200901706",

language = "English",

volume = "48",

pages = "5711--5714",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "31",

}

Warren, MR, Brayshaw, SK, Johnson, AL, Schiffers, S, Raithby, PR, Easun, TL, George, MW, Warren, JE & Teat, SJ 2009, 'Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η¹-ONO)C1] isomer', Angewandte Chemie - International Edition, vol. 48, no. 31, pp. 5711-5714. https://doi.org/10.1002/anie.200901706

Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η¹-ONO)C1] isomer. / Warren, Mark R.; Brayshaw, Simon K.; Johnson, Andrew L. et al.
In: Angewandte Chemie - International Edition, Vol. 48, No. 31, 20.07.2009, p. 5711-5714.

Research output: Journal Publication › Article › peer-review

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T2 - Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer

AU - Warren, Mark R.

AU - Brayshaw, Simon K.

AU - Johnson, Andrew L.

AU - Schiffers, Stefanie

AU - Raithby, Paul R.

AU - Easun, Timothy L.

AU - George, Michael W.

AU - Warren, John E.

AU - Teat, Simon J.

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KW - Linkage isomerism

KW - Metastable compounds

KW - Nitrites

KW - Photocrystallography

KW - Raman spectroscopy

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