Prussian blue-derived Fe2O3/sulfur composite cathode for lithium-sulfur batteries

Chongchong Zhao; Cai Shen; Fengxia Xin; Zixu Sun; Weiqiang Han

doi:10.1016/j.matlet.2014.08.115

Prussian blue-derived Fe₂O₃/sulfur composite cathode for lithium-sulfur batteries

Chongchong Zhao
, Cai Shen
, Fengxia Xin
, Zixu Sun
, Weiqiang Han

Research output: Journal Publication › Article › peer-review

77 Citations (Scopus)

Abstract

Porous Fe₂O₃ was prepared by simple annealing of preformed Prussian blue that was synthesized from a wet chemistry method. The obtained porous Fe₂O₃ nanoparticles were then mixed with sulfur and used as cathode for lithium-sulfur batteries. The porous Fe₂O₃ acts as an internal polysulfide reservoir, and thus reduces the shuttle effect. Composite cathode containing 5% porous Fe₂O₃ shows improved cycling performance as compared to that without porous Fe₂O₃. A stable reversible discharge capacity of 574.3 mAh/g was obtained after 50 cycles at 0.5 C.

Original language	English
Pages (from-to)	52-55
Number of pages	4
Journal	Materials Letters
Volume	137
DOIs	https://doi.org/10.1016/j.matlet.2014.08.115
Publication status	Published - 15 Dec 2014
Externally published	Yes

Free Keywords

Energy storage and conversion
Nanoparticles

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.matlet.2014.08.115

Cite this

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title = "Prussian blue-derived Fe2O3/sulfur composite cathode for lithium-sulfur batteries",

abstract = "Porous Fe2O3 was prepared by simple annealing of preformed Prussian blue that was synthesized from a wet chemistry method. The obtained porous Fe2O3 nanoparticles were then mixed with sulfur and used as cathode for lithium-sulfur batteries. The porous Fe2O3 acts as an internal polysulfide reservoir, and thus reduces the shuttle effect. Composite cathode containing 5\% porous Fe2O3 shows improved cycling performance as compared to that without porous Fe2O3. A stable reversible discharge capacity of 574.3 mAh/g was obtained after 50 cycles at 0.5 C.",

keywords = "Energy storage and conversion, Nanoparticles",

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AU - Zhao, Chongchong

AU - Shen, Cai

AU - Xin, Fengxia

AU - Sun, Zixu

AU - Han, Weiqiang

PY - 2014/12/15

Y1 - 2014/12/15

N2 - Porous Fe2O3 was prepared by simple annealing of preformed Prussian blue that was synthesized from a wet chemistry method. The obtained porous Fe2O3 nanoparticles were then mixed with sulfur and used as cathode for lithium-sulfur batteries. The porous Fe2O3 acts as an internal polysulfide reservoir, and thus reduces the shuttle effect. Composite cathode containing 5% porous Fe2O3 shows improved cycling performance as compared to that without porous Fe2O3. A stable reversible discharge capacity of 574.3 mAh/g was obtained after 50 cycles at 0.5 C.

AB - Porous Fe2O3 was prepared by simple annealing of preformed Prussian blue that was synthesized from a wet chemistry method. The obtained porous Fe2O3 nanoparticles were then mixed with sulfur and used as cathode for lithium-sulfur batteries. The porous Fe2O3 acts as an internal polysulfide reservoir, and thus reduces the shuttle effect. Composite cathode containing 5% porous Fe2O3 shows improved cycling performance as compared to that without porous Fe2O3. A stable reversible discharge capacity of 574.3 mAh/g was obtained after 50 cycles at 0.5 C.

KW - Energy storage and conversion

KW - Nanoparticles

UR - https://www.scopus.com/pages/publications/84907541090

U2 - 10.1016/j.matlet.2014.08.115

DO - 10.1016/j.matlet.2014.08.115

M3 - Article

AN - SCOPUS:84907541090

SN - 0167-577X

VL - 137

SP - 52

EP - 55

JO - Materials Letters

JF - Materials Letters

ER -