Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors

Inès G.T.M. Penders; Zacharias Amara; Raphael Horvath; Kai Rossen; Martyn Poliakoff; Michael W. George

doi:10.1039/c4ra15588b

Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors

Inès G.T.M. Penders
, Zacharias Amara
, Raphael Horvath
, Kai Rossen
, Martyn Poliakoff
, Michael W. George

Department of Chemical and Environmental Engineering

Research output: Journal Publication › Article › peer-review

37 Citations (Scopus)

Abstract

The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH-H₂O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.

Original language	English
Pages (from-to)	6501-6504
Number of pages	4
Journal	RSC Advances
Volume	5
Issue number	9
DOIs	https://doi.org/10.1039/c4ra15588b
Publication status	Published - 2015

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Access to Document

10.1039/c4ra15588b

Cite this

@article{97bfd26e7e8c439e9fad0e416dc80a4d,

title = "Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors",

abstract = "The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH-H2O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.",

author = "Penders, \{In{\`e}s G.T.M.\} and Zacharias Amara and Raphael Horvath and Kai Rossen and Martyn Poliakoff and George, \{Michael W.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

doi = "10.1039/c4ra15588b",

language = "English",

volume = "5",

pages = "6501--6504",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "9",

}

TY - JOUR

T1 - Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors

AU - Penders, Inès G.T.M.

AU - Amara, Zacharias

AU - Horvath, Raphael

AU - Rossen, Kai

AU - Poliakoff, Martyn

AU - George, Michael W.

PY - 2015

Y1 - 2015

N2 - The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH-H2O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.

AB - The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH-H2O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.

UR - https://www.scopus.com/pages/publications/84920860813

U2 - 10.1039/c4ra15588b

DO - 10.1039/c4ra15588b

M3 - Article

AN - SCOPUS:84920860813

SN - 2046-2069

VL - 5

SP - 6501

EP - 6504

JO - RSC Advances

JF - RSC Advances

IS - 9

ER -

Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this