'Non-classical' dihydrogen complexes of vanadium: The spectroscopic characterization of [(η5-C5H5)V(CO) 3(H2)] in solution at both cryogenic and room temperatures

Mark T. Haward; Michael W. George; Steven M. Howdle; Martyn Poliakoff

doi:10.1039/C39900000913

'Non-classical' dihydrogen complexes of vanadium: The spectroscopic characterization of [(η⁵-C₅H₅)V(CO) ₃(H₂)] in solution at both cryogenic and room temperatures

Mark T. Haward
, Michael W. George
, Steven M. Howdle
, Martyn Poliakoff^*

^*Corresponding author for this work

Research output: Journal Publication › Article › peer-review

27 Citations (Scopus)

Abstract

UV photolysis of [cpV(CO)₄] (cp = η⁵-C ₅H₅) and H₂ provides IR evidence for the formation of [cpV(CO)₃(η²-H₂)] both in n-heptane solution at 25°C and in liquid xenon solution at -78°C, where the ν(H-H) IR band of co-ordinated dihydrogen (and its HD isotopomer) can be observed; time-resolved IR (TRIR) studies provide information about the reactivity of these species at room temperature.

Original language	English
Pages (from-to)	913-915
Number of pages	3
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/C39900000913
Publication status	Published - 1990
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39900000913

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@article{fe876cf61ad346c9a6da14c944debb29,

title = "'Non-classical' dihydrogen complexes of vanadium: The spectroscopic characterization of [(η5-C5H5)V(CO) 3(H2)] in solution at both cryogenic and room temperatures",

abstract = "UV photolysis of [cpV(CO)4] (cp = η5-C 5H5) and H2 provides IR evidence for the formation of [cpV(CO)3(η2-H2)] both in n-heptane solution at 25°C and in liquid xenon solution at -78°C, where the ν(H-H) IR band of co-ordinated dihydrogen (and its HD isotopomer) can be observed; time-resolved IR (TRIR) studies provide information about the reactivity of these species at room temperature.",

author = "Haward, \{Mark T.\} and George, \{Michael W.\} and Howdle, \{Steven M.\} and Martyn Poliakoff",

year = "1990",

doi = "10.1039/C39900000913",

language = "English",

pages = "913--915",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "13",

}

'Non-classical' dihydrogen complexes of vanadium: The spectroscopic characterization of [(η⁵-C₅H₅)V(CO) ₃(H₂)] in solution at both cryogenic and room temperatures. / Haward, Mark T.; George, Michael W.; Howdle, Steven M. et al.
In: Journal of the Chemical Society D: Chemical Communications, No. 13, 1990, p. 913-915.

Research output: Journal Publication › Article › peer-review

TY - JOUR

T1 - 'Non-classical' dihydrogen complexes of vanadium

T2 - The spectroscopic characterization of [(η5-C5H5)V(CO) 3(H2)] in solution at both cryogenic and room temperatures

AU - Haward, Mark T.

AU - George, Michael W.

AU - Howdle, Steven M.

AU - Poliakoff, Martyn

PY - 1990

Y1 - 1990

N2 - UV photolysis of [cpV(CO)4] (cp = η5-C 5H5) and H2 provides IR evidence for the formation of [cpV(CO)3(η2-H2)] both in n-heptane solution at 25°C and in liquid xenon solution at -78°C, where the ν(H-H) IR band of co-ordinated dihydrogen (and its HD isotopomer) can be observed; time-resolved IR (TRIR) studies provide information about the reactivity of these species at room temperature.

AB - UV photolysis of [cpV(CO)4] (cp = η5-C 5H5) and H2 provides IR evidence for the formation of [cpV(CO)3(η2-H2)] both in n-heptane solution at 25°C and in liquid xenon solution at -78°C, where the ν(H-H) IR band of co-ordinated dihydrogen (and its HD isotopomer) can be observed; time-resolved IR (TRIR) studies provide information about the reactivity of these species at room temperature.

UR - https://www.scopus.com/pages/publications/37049089158

U2 - 10.1039/C39900000913

DO - 10.1039/C39900000913

M3 - Article

AN - SCOPUS:37049089158

SN - 0022-4936

SP - 913

EP - 915

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 13

ER -

'Non-classical' dihydrogen complexes of vanadium: The spectroscopic characterization of [(η⁵-C₅H₅)V(CO) ₃(H₂)] in solution at both cryogenic and room temperatures

Abstract

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