Irreversible network transformation in a dynamic porous host catalyzed by sulfur dioxide

Sihai Yang; Leifeng Liu; Junliang Sun; K. Mark Thomas; Andrew J. Davies; Michael W. George; Alexander J. Blake; Adrian H. Hill; Andrew N. Fitch; Chiu C. Tang; Martin Schröder

doi:10.1021/ja401061m

Irreversible network transformation in a dynamic porous host catalyzed by sulfur dioxide

Sihai Yang
, Leifeng Liu
, Junliang Sun
, K. Mark Thomas
, Andrew J. Davies
, Michael W. George
, Alexander J. Blake
, Adrian H. Hill
, Andrew N. Fitch
, Chiu C. Tang
, Martin Schröder^*

^*Corresponding author for this work

Research output: Journal Publication › Article › peer-review

135 Citations (Scopus)

Abstract

Porous NOTT-202a shows exceptionally high uptake of SO₂, 13.6 mmol g^-1 (87.0 wt %) at 268 K and 1.0 bar, representing the highest value reported to date for a framework material. NOTT-202a undergoes a distinct irreversible framework phase transition upon SO₂ uptake at 268-283 K to give NOTT-202b which has enhanced stability due to the formation of strong π···π interactions between interpenetrated networks.

Original language	English
Pages (from-to)	4954-4957
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	13
DOIs	https://doi.org/10.1021/ja401061m
Publication status	Published - 3 Apr 2013
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja401061m

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title = "Irreversible network transformation in a dynamic porous host catalyzed by sulfur dioxide",

abstract = "Porous NOTT-202a shows exceptionally high uptake of SO2, 13.6 mmol g-1 (87.0 wt \%) at 268 K and 1.0 bar, representing the highest value reported to date for a framework material. NOTT-202a undergoes a distinct irreversible framework phase transition upon SO2 uptake at 268-283 K to give NOTT-202b which has enhanced stability due to the formation of strong π···π interactions between interpenetrated networks.",

author = "Sihai Yang and Leifeng Liu and Junliang Sun and Thomas, \{K. Mark\} and Davies, \{Andrew J.\} and George, \{Michael W.\} and Blake, \{Alexander J.\} and Hill, \{Adrian H.\} and Fitch, \{Andrew N.\} and Tang, \{Chiu C.\} and Martin Schr{\"o}der",

year = "2013",

month = apr,

day = "3",

doi = "10.1021/ja401061m",

language = "English",

volume = "135",

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journal = "Journal of the American Chemical Society",

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TY - JOUR

T1 - Irreversible network transformation in a dynamic porous host catalyzed by sulfur dioxide

AU - Yang, Sihai

AU - Liu, Leifeng

AU - Sun, Junliang

AU - Thomas, K. Mark

AU - Davies, Andrew J.

AU - George, Michael W.

AU - Blake, Alexander J.

AU - Hill, Adrian H.

AU - Fitch, Andrew N.

AU - Tang, Chiu C.

AU - Schröder, Martin

PY - 2013/4/3

Y1 - 2013/4/3

N2 - Porous NOTT-202a shows exceptionally high uptake of SO2, 13.6 mmol g-1 (87.0 wt %) at 268 K and 1.0 bar, representing the highest value reported to date for a framework material. NOTT-202a undergoes a distinct irreversible framework phase transition upon SO2 uptake at 268-283 K to give NOTT-202b which has enhanced stability due to the formation of strong π···π interactions between interpenetrated networks.

AB - Porous NOTT-202a shows exceptionally high uptake of SO2, 13.6 mmol g-1 (87.0 wt %) at 268 K and 1.0 bar, representing the highest value reported to date for a framework material. NOTT-202a undergoes a distinct irreversible framework phase transition upon SO2 uptake at 268-283 K to give NOTT-202b which has enhanced stability due to the formation of strong π···π interactions between interpenetrated networks.

UR - https://www.scopus.com/pages/publications/84875771664

U2 - 10.1021/ja401061m

DO - 10.1021/ja401061m

M3 - Article

AN - SCOPUS:84875771664

SN - 0002-7863

VL - 135

SP - 4954

EP - 4957

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 13

ER -

Irreversible network transformation in a dynamic porous host catalyzed by sulfur dioxide

Abstract

ASJC Scopus subject areas

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