Graphitic carbon nitride based nanocomposites for the photocatalysis of organic contaminants under visible irradiation: Progress, limitations and future directions

Graphitic carbon nitride (g-C₃N₄) has drawn great attention recently because of its visible light response, suitable energy band gap, good redox ability, and metal-free nature. g-C₃N₄ can absorb visible light directly, therefore has better photocatalytic ability under solar irradiation and is more energy-efficient than TiO₂. However, pure g-C₃N₄ still has the drawbacks of insufficient light absorption, small surface area and fast recombination of photogenerated electron and hole pairs. This review summarizes the recent progress in the development of g-C₃N₄ nanocomposites to photodegrade organic contaminants in water. Element doping especially by potassium has been reported to be an efficient method to promote the degradation efficacy. In addition, compound doping improves photodegradation performance of g-C₃N₄, especially Ag₃PO₄-g-C₃N₄ which can completely degrade 10 mg L⁻¹ of methyl orange under visible light irradiation in 5 min, with the rate constant (k) as high as 0.236 min⁻¹. Moreover, co-doping enhances the photodegradation rate of multiple contaminants while immobilization significantly improves catalyst stability. Most of g-C₃N₄ composites possess high reusability enabling their practical applications in wastewater treatment. Furthermore, environmental conditions such as solution pH, reaction temperature, dissolved oxygen, and dissolved organic matter all have important effects on the photocatalytic ability of g-C₃N₄ photocatalyst. Future work should focus on the synthesis of innovative g-C₃N₄ nanocomposites for the efficient removal of organic contaminants in water and wastewater.