Formation and reactivity of organometallic alkane complexes

Alexander J. Cowan; Michael W. George

doi:10.1016/j.ccr.2008.05.008

Formation and reactivity of organometallic alkane complexes

Alexander J. Cowan, Michael W. George

Research output: Journal Publication › Review article › peer-review

70 Citations (Scopus)

Abstract

Organometallic alkane complexes are highly reactive species that have been shown to be key intermediates in the C-H activation of alkanes by transition metal centres. Organometallic alkane complexes were first identified in low temperature matrices over 30 years ago and now sufficiently long-lived examples have been characterised by NMR spectroscopy. We provide a brief overview of the study of these key reactive intermediates and describe recent studies on the characterisation of organometallic alkane complexes and their related C-H activation using fast time-resolved infrared (TRIR) spectroscopy.

Original language	English
Pages (from-to)	2504-2511
Number of pages	8
Journal	Coordination Chemistry Reviews
Volume	252
Issue number	23-24
DOIs	https://doi.org/10.1016/j.ccr.2008.05.008
Publication status	Published - Dec 2008
Externally published	Yes

Keywords

Alkane complexes
C-H activation
Sigma complexes
Time-resolved infrared
Time-resolved spectroscopy

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ccr.2008.05.008

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title = "Formation and reactivity of organometallic alkane complexes",

abstract = "Organometallic alkane complexes are highly reactive species that have been shown to be key intermediates in the C-H activation of alkanes by transition metal centres. Organometallic alkane complexes were first identified in low temperature matrices over 30 years ago and now sufficiently long-lived examples have been characterised by NMR spectroscopy. We provide a brief overview of the study of these key reactive intermediates and describe recent studies on the characterisation of organometallic alkane complexes and their related C-H activation using fast time-resolved infrared (TRIR) spectroscopy.",

keywords = "Alkane complexes, C-H activation, Sigma complexes, Time-resolved infrared, Time-resolved spectroscopy",

author = "Cowan, \{Alexander J.\} and George, \{Michael W.\}",

note = "Funding Information: We thank all current and previous members of the MWG research group whose work is referenced above. The EPSRC, UKCCSC and the University of Nottingham for financial support. The STFC for access to the Central Laser Facility (CLF) at the Rutherford Appleton Laboratory and the staff of the CLF for useful discussions and experimental help.",

year = "2008",

month = dec,

doi = "10.1016/j.ccr.2008.05.008",

language = "English",

volume = "252",

pages = "2504--2511",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

publisher = "Elsevier B.V.",

number = "23-24",

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TY - JOUR

T1 - Formation and reactivity of organometallic alkane complexes

AU - Cowan, Alexander J.

AU - George, Michael W.

N1 - Funding Information: We thank all current and previous members of the MWG research group whose work is referenced above. The EPSRC, UKCCSC and the University of Nottingham for financial support. The STFC for access to the Central Laser Facility (CLF) at the Rutherford Appleton Laboratory and the staff of the CLF for useful discussions and experimental help.

PY - 2008/12

Y1 - 2008/12

N2 - Organometallic alkane complexes are highly reactive species that have been shown to be key intermediates in the C-H activation of alkanes by transition metal centres. Organometallic alkane complexes were first identified in low temperature matrices over 30 years ago and now sufficiently long-lived examples have been characterised by NMR spectroscopy. We provide a brief overview of the study of these key reactive intermediates and describe recent studies on the characterisation of organometallic alkane complexes and their related C-H activation using fast time-resolved infrared (TRIR) spectroscopy.

AB - Organometallic alkane complexes are highly reactive species that have been shown to be key intermediates in the C-H activation of alkanes by transition metal centres. Organometallic alkane complexes were first identified in low temperature matrices over 30 years ago and now sufficiently long-lived examples have been characterised by NMR spectroscopy. We provide a brief overview of the study of these key reactive intermediates and describe recent studies on the characterisation of organometallic alkane complexes and their related C-H activation using fast time-resolved infrared (TRIR) spectroscopy.

KW - Alkane complexes

KW - C-H activation

KW - Sigma complexes

KW - Time-resolved infrared

KW - Time-resolved spectroscopy

UR - https://www.scopus.com/pages/publications/55049091771

U2 - 10.1016/j.ccr.2008.05.008

DO - 10.1016/j.ccr.2008.05.008

M3 - Review article

AN - SCOPUS:55049091771

SN - 0010-8545

VL - 252

SP - 2504

EP - 2511

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

IS - 23-24

ER -

Formation and reactivity of organometallic alkane complexes

Abstract

Keywords

ASJC Scopus subject areas

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