Cleaner continuous photo-oxidation using singlet oxygen in supercritical carbon dioxide

Richard A. Bourne; Xue Han; Martyn Poliakoff; Michael W. George

doi:10.1002/anie.200901731

Cleaner continuous photo-oxidation using singlet oxygen in supercritical carbon dioxide

Richard A. Bourne
, Xue Han
, Martyn Poliakoff
, Michael W. George

Research output: Journal Publication › Article › peer-review

88 Citations (Scopus)

Abstract

High pressure under the spotlight: A new milliliter-scale reactor is developed for using supercritical CO ₂ to perform continuous photo-oxidation reactions. Changing from a traditional microliter-scale batch reaction to 8 hours of reaction using the new reactor gives a 3000-fold scale-up of the oxidation of α-terpinene (see picture).

Original language	English
Pages (from-to)	5322-5325
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	29
DOIs	https://doi.org/10.1002/anie.200901731
Publication status	Published - 6 Jul 2009
Externally published	Yes

Free Keywords

Oxidation
Photochemistry
Singlet oxygen
Supercritical fluids
Sustainable chemistry

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200901731

Cite this

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abstract = "High pressure under the spotlight: A new milliliter-scale reactor is developed for using supercritical CO 2 to perform continuous photo-oxidation reactions. Changing from a traditional microliter-scale batch reaction to 8 hours of reaction using the new reactor gives a 3000-fold scale-up of the oxidation of α-terpinene (see picture).",

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AU - Han, Xue

AU - Poliakoff, Martyn

AU - George, Michael W.

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Y1 - 2009/7/6

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AB - High pressure under the spotlight: A new milliliter-scale reactor is developed for using supercritical CO 2 to perform continuous photo-oxidation reactions. Changing from a traditional microliter-scale batch reaction to 8 hours of reaction using the new reactor gives a 3000-fold scale-up of the oxidation of α-terpinene (see picture).

KW - Oxidation

KW - Photochemistry

KW - Singlet oxygen

KW - Supercritical fluids

KW - Sustainable chemistry

UR - https://www.scopus.com/pages/publications/70349931208

U2 - 10.1002/anie.200901731

DO - 10.1002/anie.200901731

M3 - Article

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SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

Cleaner continuous photo-oxidation using singlet oxygen in supercritical carbon dioxide

Abstract

Free Keywords

ASJC Scopus subject areas

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