Additive manufacture of three dimensional nanocomposite based objects through multiphoton fabrication

Yaan Liu; Qin Hu; Fan Zhang; Christopher Tuck; Derek Irvine; Richard Hague; Yinfeng He; Marco Simonelli; Graham A. Rance; Emily F. Smith; Ricky D. Wildman

doi:10.3390/polym8090325

Additive manufacture of three dimensional nanocomposite based objects through multiphoton fabrication

Yaan Liu
, Qin Hu
, Fan Zhang
, Christopher Tuck
, Derek Irvine
, Richard Hague
, Yinfeng He
, Marco Simonelli
, Graham A. Rance
, Emily F. Smith
, Ricky D. Wildman^*

^*Corresponding author for this work

CBI Intelligent Manufacturing Centre

Research output: Journal Publication › Article › peer-review

22 Citations (Scopus)

Abstract

Three-dimensional structures prepared from a gold-polymer composite formulation have been fabricated using multiphoton lithography. In this process, gold nanoparticles were simultaneously formed through photoreduction whilst polymerisation of two possible monomers was promoted. The monomers, trimethylopropane triacrylate (TMPTA) and pentaerythritol triacrylate (PETA) were mixed with a gold salt, but it was found that the addition of a ruthenium(II) complex enhanced both the geometrical uniformity and integrity of the polymerised/reduced material, enabling the first production of 3D gold-polymer structures by single step multiphoton lithography.

Original language	English
Article number	325
Journal	Polymers
Volume	8
Issue number	9
DOIs	https://doi.org/10.3390/polym8090325
Publication status	Published - 1 Sept 2016

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 9 Industry, Innovation, and Infrastructure

Free Keywords

3D printing
Additive manufacturing
Gold nanoparticles
Metal reduction
Multiphoton fabrication (MF)
Nanocomposite
Polymerisation
Two-photon lithography (TPL)

ASJC Scopus subject areas

General Chemistry
Polymers and Plastics

Access to Document

10.3390/polym8090325

Cite this

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title = "Additive manufacture of three dimensional nanocomposite based objects through multiphoton fabrication",

abstract = "Three-dimensional structures prepared from a gold-polymer composite formulation have been fabricated using multiphoton lithography. In this process, gold nanoparticles were simultaneously formed through photoreduction whilst polymerisation of two possible monomers was promoted. The monomers, trimethylopropane triacrylate (TMPTA) and pentaerythritol triacrylate (PETA) were mixed with a gold salt, but it was found that the addition of a ruthenium(II) complex enhanced both the geometrical uniformity and integrity of the polymerised/reduced material, enabling the first production of 3D gold-polymer structures by single step multiphoton lithography.",

keywords = "3D printing, Additive manufacturing, Gold nanoparticles, Metal reduction, Multiphoton fabrication (MF), Nanocomposite, Polymerisation, Two-photon lithography (TPL)",

author = "Yaan Liu and Qin Hu and Fan Zhang and Christopher Tuck and Derek Irvine and Richard Hague and Yinfeng He and Marco Simonelli and Rance, \{Graham A.\} and Smith, \{Emily F.\} and Wildman, \{Ricky D.\}",

note = "Publisher Copyright: {\textcopyright} 2016 by the authors; licensee MDPI, Basel, Switzerland.",

year = "2016",

month = sep,

day = "1",

doi = "10.3390/polym8090325",

language = "English",

volume = "8",

journal = "Polymers",

issn = "2073-4360",

publisher = "MDPI Multidisciplinary Digital Publishing Institute",

number = "9",

}

TY - JOUR

T1 - Additive manufacture of three dimensional nanocomposite based objects through multiphoton fabrication

AU - Liu, Yaan

AU - Hu, Qin

AU - Zhang, Fan

AU - Tuck, Christopher

AU - Irvine, Derek

AU - Hague, Richard

AU - He, Yinfeng

AU - Simonelli, Marco

AU - Rance, Graham A.

AU - Smith, Emily F.

AU - Wildman, Ricky D.

PY - 2016/9/1

Y1 - 2016/9/1

N2 - Three-dimensional structures prepared from a gold-polymer composite formulation have been fabricated using multiphoton lithography. In this process, gold nanoparticles were simultaneously formed through photoreduction whilst polymerisation of two possible monomers was promoted. The monomers, trimethylopropane triacrylate (TMPTA) and pentaerythritol triacrylate (PETA) were mixed with a gold salt, but it was found that the addition of a ruthenium(II) complex enhanced both the geometrical uniformity and integrity of the polymerised/reduced material, enabling the first production of 3D gold-polymer structures by single step multiphoton lithography.

AB - Three-dimensional structures prepared from a gold-polymer composite formulation have been fabricated using multiphoton lithography. In this process, gold nanoparticles were simultaneously formed through photoreduction whilst polymerisation of two possible monomers was promoted. The monomers, trimethylopropane triacrylate (TMPTA) and pentaerythritol triacrylate (PETA) were mixed with a gold salt, but it was found that the addition of a ruthenium(II) complex enhanced both the geometrical uniformity and integrity of the polymerised/reduced material, enabling the first production of 3D gold-polymer structures by single step multiphoton lithography.

KW - 3D printing

KW - Additive manufacturing

KW - Gold nanoparticles

KW - Metal reduction

KW - Multiphoton fabrication (MF)

KW - Nanocomposite

KW - Polymerisation

KW - Two-photon lithography (TPL)

UR - https://www.scopus.com/pages/publications/84990044451

U2 - 10.3390/polym8090325

DO - 10.3390/polym8090325

M3 - Article

AN - SCOPUS:84990044451

SN - 2073-4360

VL - 8

JO - Polymers

JF - Polymers

IS - 9

M1 - 325

ER -

Additive manufacture of three dimensional nanocomposite based objects through multiphoton fabrication

Abstract

UN SDGs

Free Keywords

ASJC Scopus subject areas

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