Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior

Youbing Li; Mian Li; Jun Lu; Baokai Ma; Zhipan Wang; Ling-Zhi Cheong; Kan Luo; Xianhu Zha; Ke Chen; Per O. A. Persson; Lars Hultman; Per Eklund; Cai Shen; Qigang Wang; Jianming Xue; Shiyu Du; Zhengren Huang; Zhifang Chai; Qing Huang

doi:10.1021/ACSNANO.9B03530

Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior

Youbing Li, Mian Li, Jun Lu, Baokai Ma, Zhipan Wang, Ling-Zhi Cheong, Kan Luo, Xianhu Zha, Ke Chen, Per O. A. Persson, Lars Hultman, Per Eklund, Cai Shen, Qigang Wang, Jianming Xue, Shiyu Du, Zhengren Huang, Zhifang Chai, Qing Huang

Research output: Journal Publication › Article › peer-review

Abstract

A Ti3(AlxCu1–x)C2 phase with Cu atoms with a degree of ordering in the A plane is synthesized through the A site replacement reaction in CuCl2 molten salt. The weakly bonded single-atom-thick Cu layers in a Ti3(AlxCu1–x)C2 MAX phase provide actives sites for catalysis chemistry. As-synthesized Ti3(AlxCu1–x)C2 presents unusual peroxidase-like catalytic activity similar to that of natural enzymes. A fabricated Ti3(AlxCu1–x)C2/chitosan/glassy carbon electrode biosensor prototype also exhibits a low detection limit in the electrochemical sensing of H2O2. These results have broad implications for property tailoring in a nanolaminated MAX phase by replacing the A site with late transition elements.

Original language	English
Pages (from-to)	9198−9205
Number of pages	7
Journal	ACS Nano
Issue number	13
DOIs	https://doi.org/10.1021/ACSNANO.9B03530
Publication status	Published - 2019
Externally published	Yes

Keywords

nanolaminate
MAX phase
copper
catalysis
replacement reaction

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10.1021/ACSNANO.9B03530

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Li, Y., Li, M., Lu, J., Ma, B., Wang, Z., Cheong, L.-Z., Luo, K., Zha, X., Chen, K., Persson, P. O. A., Hultman, L., Eklund, P., Shen, C., Wang, Q., Xue, J., Du, S., Huang, Z., Chai, Z., & Huang, Q. (2019). Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior. ACS Nano, (13), 9198−9205. https://doi.org/10.1021/ACSNANO.9B03530

@article{aa8b8832dcb743ac9d444241de8b46f0,

title = "Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior",

abstract = "A Ti3(AlxCu1–x)C2 phase with Cu atoms with a degree of ordering in the A plane is synthesized through the A site replacement reaction in CuCl2 molten salt. The weakly bonded single-atom-thick Cu layers in a Ti3(AlxCu1–x)C2 MAX phase provide actives sites for catalysis chemistry. As-synthesized Ti3(AlxCu1–x)C2 presents unusual peroxidase-like catalytic activity similar to that of natural enzymes. A fabricated Ti3(AlxCu1–x)C2/chitosan/glassy carbon electrode biosensor prototype also exhibits a low detection limit in the electrochemical sensing of H2O2. These results have broad implications for property tailoring in a nanolaminated MAX phase by replacing the A site with late transition elements.",

keywords = "nanolaminate, MAX phase, copper, catalysis, replacement reaction",

author = "Youbing Li and Mian Li and Jun Lu and Baokai Ma and Zhipan Wang and Ling-Zhi Cheong and Kan Luo and Xianhu Zha and Ke Chen and Persson, {Per O. A.} and Lars Hultman and Per Eklund and Cai Shen and Qigang Wang and Jianming Xue and Shiyu Du and Zhengren Huang and Zhifang Chai and Qing Huang",

year = "2019",

doi = "10.1021/ACSNANO.9B03530",

language = "English",

pages = "9198−9205",

journal = "ACS Nano",

issn = "1936-0851",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior

AU - Li, Youbing

AU - Li, Mian

AU - Lu, Jun

AU - Ma, Baokai

AU - Wang, Zhipan

AU - Cheong, Ling-Zhi

AU - Luo, Kan

AU - Zha, Xianhu

AU - Chen, Ke

AU - Persson, Per O. A.

AU - Hultman, Lars

AU - Eklund, Per

AU - Shen, Cai

AU - Wang, Qigang

AU - Xue, Jianming

AU - Du, Shiyu

AU - Huang, Zhengren

AU - Chai, Zhifang

AU - Huang, Qing

PY - 2019

Y1 - 2019

N2 - A Ti3(AlxCu1–x)C2 phase with Cu atoms with a degree of ordering in the A plane is synthesized through the A site replacement reaction in CuCl2 molten salt. The weakly bonded single-atom-thick Cu layers in a Ti3(AlxCu1–x)C2 MAX phase provide actives sites for catalysis chemistry. As-synthesized Ti3(AlxCu1–x)C2 presents unusual peroxidase-like catalytic activity similar to that of natural enzymes. A fabricated Ti3(AlxCu1–x)C2/chitosan/glassy carbon electrode biosensor prototype also exhibits a low detection limit in the electrochemical sensing of H2O2. These results have broad implications for property tailoring in a nanolaminated MAX phase by replacing the A site with late transition elements.

AB - A Ti3(AlxCu1–x)C2 phase with Cu atoms with a degree of ordering in the A plane is synthesized through the A site replacement reaction in CuCl2 molten salt. The weakly bonded single-atom-thick Cu layers in a Ti3(AlxCu1–x)C2 MAX phase provide actives sites for catalysis chemistry. As-synthesized Ti3(AlxCu1–x)C2 presents unusual peroxidase-like catalytic activity similar to that of natural enzymes. A fabricated Ti3(AlxCu1–x)C2/chitosan/glassy carbon electrode biosensor prototype also exhibits a low detection limit in the electrochemical sensing of H2O2. These results have broad implications for property tailoring in a nanolaminated MAX phase by replacing the A site with late transition elements.

KW - nanolaminate

KW - MAX phase

KW - copper

KW - catalysis

KW - replacement reaction

UR - https://publons.com/publon/21414380/

U2 - 10.1021/ACSNANO.9B03530

DO - 10.1021/ACSNANO.9B03530

M3 - Article

SN - 1936-0851

SP - 9198−9205

JO - ACS Nano

JF - ACS Nano

IS - 13

ER -

Single-atom-thick active layers realized in nanolaminated Ti-3(AlxCu1-x)C-2 and its artificial enzyme behavior

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